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It's simply chemical changes because of temperature and the color change is probably due to too much time in the freezer. It might taste fine but if too long in the freezer, as with all other foods, the cabbage may also have lost nutrients.
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Did you know that if you freeze a raw head of cabbage for 2 or 3 days you don't have to scald it to make cabbage rolls. The cabbage is soft when it thaws and easy to handle.
For making stuffed cabbage rolls, put the cabbage in the freezer (whole) for a few hours until it's pretty solid.
